Stereoselective synthesis of insect sex pheromone analogs having a fluorine atom on their double bonds

摘要

Insect sex pheromone analogs having a fluorine atom on their double bonds,(9E,11E)-1-acetoxy-9-fluorotetradecadiene, (10E,12E)-13-fluorohexadecadien-1-ol,(9Z,11E)-1-acetoxy-9-fluorotetradecadiene, (10E,12Z)-13-fluorohexadecadien-1-olwere stereoselectively synthesized using cross-coupling reactions of alkenylboraneswith (E)- or (Z)-2-fluoro-1-iodo-1-alkenes, stereoselectively prepared from 1-alkynes byour currently developed methods.